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Understanding Dangerous Goods Classes for Safe Air Shipping

Dangerous goods are items that can harm people, property, or the environment if not handled correctly. These include things like flammable liquids, toxic chemicals, batteries, gases, and even some everyday products. In air cargo, moving dangerous goods safely is critical — and it’s not as simple as just packing and shipping.

To help keep everyone safe, the United Nations has grouped dangerous goods into 9 main classes, based on the type of hazard they present. Some of these classes are also split into smaller divisions.

Each dangerous good has a UN number and a proper shipping name, and must be packaged, labeled, and documented correctly. That’s where the IATA Dangerous Goods Regulations (DGR) come in — they provide detailed rules for shipping these items by air.

If you're unsure about how an item is classified, you can check the Safety Data Sheet (SDS) from the manufacturer. This document helps you identify the hazards and make sure you're following the right steps. If there's no SDS available, contact the manufacturer or a specialist to confirm the classification.

dangerous-goods-classes

Dangerous Goods Classes

The United Nations categorizes Dangerous Goods into nine classes, ensuring risks are effectively communicated throughout the transport chain.


Class 1 – Explosives

Explosives can rapidly combust or detonate due to chemical reactions. Their handling requires strict compliance with transport regulations.

Why Are They Regulated? Explosives generate high-pressure gases, heat, light, and sound, posing significant risks.

Subcategories:

  • 1.1 – Mass explosion hazards

  • 1.2 – Fragment projection risk

  • 1.3 – Fire hazards with minor explosion effects

  • 1.4 – Low-risk, packaging-contained hazards

  • 1.5 – Insensitive explosives with mass explosion potential

  • 1.6 – Extremely insensitive explosives with no mass explosion risk

Common Examples: Fireworks, flares, ammunition, detonators, TNT, airbags.


Class 2 – Gases

These are substances in a gaseous state at standard temperatures, including compressed, liquefied, and refrigerated gases.

Why Are They Regulated? They can be flammable, toxic, oxidizing, or asphyxiating, posing serious transport risks.

Subcategories:

  • 2.1 – Flammable gases

  • 2.2 – Non-flammable, non-toxic gases

  • 2.3 – Toxic gases

Common Examples: Propane, hydrogen, oxygen, refrigerant gases.


Class 3 – Flammable Liquids

Liquids that emit flammable vapors below 60-65°C.

Why Are They Regulated? They are highly volatile and can cause large-scale fires.

Common Examples: Gasoline, diesel, alcohols, acetone, varnishes, methanol.


Class 4 – Flammable Solids & Reactive Materials

These substances ignite easily, react with air, or release flammable gases upon contact with water.

Why Are They Regulated? They can spontaneously combust or cause fires through friction.

Subcategories:

  • 4.1 – Flammable solids

  • 4.2 – Spontaneously combustible substances

  • 4.3 – Substances emitting flammable gases when wet

Common Examples: Matches, sodium batteries, phosphorus, nitrocellulose.


Class 5 – Oxidizers & Organic Peroxides

These substances enhance combustion or decompose explosively.

Why Are They Regulated? They can cause fires or violent reactions.

Subcategories:

  • 5.1 – Oxidizing substances

  • 5.2 – Organic peroxides

Common Examples: Ammonium nitrate, hydrogen peroxide, potassium permanganate.


Class 6 – Toxic & Infectious Substances

Includes chemicals harmful to human health and biological materials containing pathogens.

Why Are They Regulated? They can cause poisoning, illness, or environmental contamination.

Subcategories:

  • 6.1 – Toxic substances

  • 6.2 – Infectious substances

Common Examples: Pesticides, cyanides, arsenic compounds, medical waste.


Class 7 – Radioactive Materials

Materials emitting ionizing radiation.

Why Are They Regulated? Exposure can lead to severe health effects and contamination.

Common Examples: Uranium, plutonium, medical isotopes.


Class 8 – Corrosives

These substances cause severe damage upon contact.

Why Are They Regulated? They can burn skin, corrode metals, and release harmful fumes.

Common Examples: Sulfuric acid, hydrochloric acid, bromine.


Class 9 – Miscellaneous Dangerous Goods

Includes hazardous substances that don’t fit other classifications but still pose transport risks.

Why Are They Regulated? They may be environmentally hazardous, reactive, or pose unexpected dangers.

Common Examples: Dry ice, lithium batteries, magnetized materials.


Here’s a revised and easier-to-read version of your text:

Requirements for Shipping Dangerous Goods and Hazardous Materials

When shipping dangerous goods or hazardous materials, it’s essential for exporters, importers, and carriers to understand the necessary precautions and regulations. Complying with these requirements ensures safety, legal compliance, and smooth operations. Here’s what you need to know when shipping dangerous goods.


Dangerous Goods Packaging

Shipping dangerous goods internationally requires meeting specific packaging standards. The packaging must be tested and certified by an authorized body, such as the United Nations. Depending on the class of dangerous goods, you may need multiple layers of packaging based on factors like transport mode, quantity, and handling needs.

packaging-of-dangerous-goods

It’s also critical to ensure proper segregation of dangerous goods during packaging. Each substance has compatibility restrictions, which can be found in a dangerous goods compatibility chart to guide you in safely organizing your shipment.

segregation-of-dangerous-goods

Dangerous Goods Labeling

Proper labeling is one of the most vital parts of shipping hazardous materials. The label provides essential information for everyone handling the shipment, including warehouse staff, customs officers, and delivery personnel. It indicates the dangerous goods class, helping handlers take the proper precautions during transport.

In addition to warning labels, some hazardous materials require additional labels specifying handling instructions, weight, cautions, orientation guidelines, and more. Additionally, tamper-evident seals may be needed on some packages. The shipper’s and recipient’s details should also appear on the label in many cases.

Labels must be clearly visible and placed on the package in a prominent location. Ensure that the label’s background color contrasts sharply with the text for maximum readability, and avoid obscuring it with other markings or labels.



Dangerous Goods Declaration

When shipping dangerous goods internationally, you must formally declare them in the shipment. This declaration involves providing specific documents, such as Commercial Invoices, Cargo Reports, and an Air Waybill (for air freight). Some carriers may also require a Dangerous Goods Note, which outlines details about the materials being shipped, including their storage, handling, and customs clearance requirements.


Customs Clearance Procedures

Dangerous goods shipments must meet specific customs requirements, both for imports and exports. Before shipping, it’s important to check whether the shipment of certain dangerous goods is prohibited in the destination country. If the goods are not prohibited, confirm any restrictions that might apply based on the class of dangerous goods.

Each country has unique customs requirements that cover aspects like quantity, packaging, labeling, handling, and declarations. Some dangerous goods shipments may also require special permits for customs clearance. These permits must be obtained from the relevant authorities before the shipment can proceed.

This version breaks down the steps in a more organized, easy-to-follow manner, with headings and bullet points to highlight key information.


Safe Air Shipping of Dangerous Goods

Transporting hazardous materials by air requires strict adherence to safety regulations.

  1. Declaration & Documentation – Shippers must correctly declare the goods and complete the Dangerous Goods Declaration.

  2. Packaging & Labeling – Secure, durable packaging must prevent leaks, withstand pressure changes, and include clear labels.

  3. Acceptance & Compliance Checks – Airlines verify shipments using IATA’s Dangerous Goods Checklist.

  4. Handling & Storage – Proper segregation and secure loading prevent accidents.

  5. Final Transport & Delivery – Only approved goods are placed in freight containers or Unit Load Devices (ULDs).

By following these steps, hazardous goods can be safely transported with minimal risk.


Stellavia: Your Trusted Partner in DG Transportation

At Stellavia, we specialize in the safe, compliant, and efficient transportation of Dangerous Goods worldwide. Our DG-certified team ensures:

  • Proper documentation and labeling

  • Secure packaging and handling

  • Compliance with international safety standards

  • Efficient and timely delivery to global destinations

Whether you're shipping hazardous chemicals, lithium batteries, or medical supplies, Stellavia provides safe, reliable, and regulatory-compliant air cargo solutions. Contact us today to learn more about our Dangerous Goods air freight services!


 
 
 
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